CAS 106-38-7 MFCD00000109-4-Bromotoluene 对溴甲苯 -LabNovo

4-Bromotoluene 对溴甲苯

CAS 106-38-7 MFCD00000109

化学结构图

SMILES: Cc1ccc(Br)cc1

化学属性

Mol. Formula	C7H7Br
Mol. Weight	171
Density	1.39
Flash Point	85°(185°F)
TSCA	Yes
Boiling Point	184
Melting Point	26-29
Refractive index	1.5477
Solubility	不溶于水，溶于乙醇、乙醚、苯。

别名和识别编码

Chemical Name	4-Bromotoluene
CAS Number	106-38-7
EC Number	203-391-8
Beilstein Registry Number	1903636
MDL Number	MFCD00000109
Synonym	1-BROMO-4-METHYLBENZENE 1-Bromo-4-methylbenzene 1-Bromo-4-methylbenzene; 4-Bromo-1-methylbenzene; 4-Methyl-1-bromobenzene; p-Methylbromobenzene; p-Methylphenyl bromide; p-Tolyl bromide 4-BROMOTOLUENE 4-Methylbromobenzene 4-Methylphenyl bromide 4-Tolyl bromide 4-bromo-toluene 4-methylphenyl bromide 4-溴甲苯 4-甲基溴苯 p-Bromtoluol p-Methylbromobenzene p-Methylphenyl bromide p-br p-bromtoluene p-tolyl bromide AKOS BBS-00004360 Benzene, 1-bromo-4-methyl- P-BROMOTOLUENE P-溴甲苯 benzene, 1-bromo-4-methyl- p-Methylbromobenzene p-Methylphenyl bromide toluene, 4-bromo- 对甲(基)溴苯对甲基溴苯
Merck Number	14,1439
PubChem Substance ID	87563667
Reaxys-RN	1903636
Chemical Name Translation	对溴甲苯
Wiswesser Line Notation	ER D1
LabNetwork Molecule ID	LN00196796
InChI	InChI=1S/C7H7Br/c1-6-2-4-7(8)5-3-6/h2-5H,1H3

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产品应用

用于有机合成。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R38 Irritating to skin 刺激皮肤
R51/53

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSXS7965600

Hazard statements

H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes 9

UN Number 3077 UN 3077 9/PG 3

Packing GroupIII

Hazard Class9

Warnings 危化品目录(2015)

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1300 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 18(4),55,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1741 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 20(12),52,1976

Restrict 危险品

其他信息

Sigma Aldrich:106-38-7(sigmaaldrich)
MOL 文件:106-38-7.mol
毒性分级:中毒
储运特性:库房通风低温干燥; 与氧化剂、食品原料分开储运
类别:有毒物品
Acros Organics:4-溴甲苯 4-Bromotoluene, 99%(106-38-7)
图谱信息:对溴甲苯(106-38-7)红外图谱(IR1) 对溴甲苯(106-38-7)红外图谱(IR2) 对溴甲苯(106-38-7)质谱(MS) 对溴甲苯(106-38-7)核磁图( 1 HNMR) 对溴甲苯(106-38-7)核磁图( 13 CNMR) 对溴甲苯(106-38-7)红外图谱(IR3)
方法一:由对甲苯胺重氮化、置换而得。先将硫酸水溶液趁热加入粉碎的对甲苯胺中，冷至5℃，慢慢加入亚硝酸钠水溶液至淀粉碘化钾试纸变蓝。然后加少量尿素破坏过量的亚硝酸钠。再将合成好的溴化亚铜加入氢溴酸，加热至沸腾，然后慢慢加入上述重氮盐，将其蒸馏至不出油状物为止。洗涤、干燥、过滤，常压蒸馏，收集183-185℃馏分而得成品。溴化亚铜-氢溴酸溶液可按下法配制：把硫酸铜、铜屑、溴化钠二水物、浓硫酸和水的混合物加热回流3-4h，至溶液变成淡黄色，即为溴化亚铜-氢溴酸溶液。
海关编码:29036990
可燃性危险特性:明火可燃; 受热分解有毒溴化物气体
用途二:用于有机合成
外观性质:白色结晶。
急性毒性:腹腔-小鼠 LD50: 1741 毫克/公斤
下游产品:(S)-7,7'-双[二(对甲基苯基羟亚磷基))-1,1'-螺二氢茚 --> 2-二环己膦基-2'-(N,N-二甲胺)-联苯 --> 4-溴苯甲醛 --> 双二苯基磷酰联萘 --> 双二苯基磷酰联萘 --> 三对苯甲基膦 --> 4-溴苯甲酸 --> 4-甲氧羰基苯硼酸 --> 4-苯基甲酰氨苯基硼酸 --> 2-(4-甲基苯基)吡啶 --> 4-正丁基甲苯 --> 对溴溴苄
Alfa Aesar:4-溴甲苯,98% 4-Bromotoluene, 98%(106-38-7)
用途一:用作有机合成原料及中间体，用于医药工业
溶于乙醇、乙醚和苯，不溶于水。
MSDS 信息:对甲基溴苯(106-38-7).msds
灭火剂:二氧化碳、砂土、泡沫、砂土
对溴甲苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 81002725 4-溴甲苯;对溴甲苯 50g 78元 2011/04/16 B0661 4-溴甲苯 4-Bromotoluene 500G 1120元 2011/04/16 B0661 4-溴甲苯 4-Bromotoluene 25G 218元
TCI Shanghai:4-溴甲苯 4-Bromotoluene,>;99.0%(GC)(106-38-7)
上游原料:硫酸铜 --> 溴化钠 --> 溴化亚铜 --> 对甲苯胺 --> 淀粉-碘化钾试纸 --> 钼酸钠 --> 铜屑