Methylcyclohexane 甲基环己烷

CAS 108-87-2 MFCD00001497

化学结构图

108-87-2
SMILES: Cc1ccccc1

化学属性

Mol. FormulaC7H14
Mol. Weight98.19
Autoignition Point545 °F
Refractive index1.4220 to 1.4240
Vapor Density3.4 (vs air)
Vapor Pressure37 mmHg ( 20 °C)
Density0.77
Melting Point-126
Flash Point-3.89°C
TSCAYes
Solubility不溶于水，溶于乙醇、乙醚、丙酮、苯、石油醚、四氯化碳等。
Stability对湿度敏感
Boiling Point-
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameMethylcyclohexane
MDL Number-
CAS Number108-87-2
Synonym Cyclohexane, methyl- {LY} Cyclohexane, methyl- {} {LY} Cyclohexane, methyl- {} {} {LY} Cyclohexane, methyl- {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclohexane, methyl- {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID87572329
EC Number203-624-3
Beilstein Registry Number505972
Merck Number6047
Reaxys-RN505972
Chemical Name Translation甲基环己烷
Wiswesser Line NotationL6TJ A1
LabNetwork Molecule IDLN00163329
Canonical SMILESCC1CCCCC1
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分类

  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Chemical Class, Chromatography, Environmental Standards, Hydrocarbons, M, META - METH, Neats and Solutions, Volatiles/ Semivolatiles, 分析/色谱
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chemical Class, Chromatography, Environmental Standards, Hydrocarbons, M, META - METH, Neats and Solutions, Volatiles/ Semivolatiles
  • {SNA} Anhydrous Solvents, Solvent Bottles,

产品应用

  • 用作溶剂、色谱分析标准物质，以及作为校正温度计的标准，也用于有机合成

相关文献及参考

  • For use as a solvent in the preparation of unsolvated Grignard reagents from an alkyl halide and Mg powder: Org. Synth. Coll., 5, 1141 (1973).
  • Short: II/25D
  • Merck:14,6047 Beilstein: 5,IV,94
  • Merck:14,6047
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H315 Causes skin irritation 会刺激皮肤
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSGV6125000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P331+P330
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340+P312
  • P305+P351+P338+P337+P313
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2296 UN2296
Risk Statements
  • R11 Highly flammable 非常易燃
  • R38 Irritating to skin 刺激皮肤
  • R51/53
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Hazard Codes 3
Hazard Class3
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 41500 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,82,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 15227 ppm/1H
TOXIC EFFECTS :
   Behavioral - general anesthetic
   Behavioral - convulsions or effect on seizure threshold
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,323,1943

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 4 gm/kg
TOXIC EFFECTS :
   Gastrointestinal - hypermotility, diarrhea
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 25,199,1943

Restrict -

其他信息

  • 甲基环己烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80083090 甲基环已烷 500ml 250元 2011/08/23 40031361 甲基环己烷;六氢甲苯;环己基甲烷 2ml 48元 2011/08/23 80083080 甲基环己烷;六氢甲苯;环己基甲烷 500ml 280元
  • 毒性分级:中毒
  • 下游产品:庚烷 --> 利尿酸 --> 2,5-二甲基-1,3-恶唑-4-甲醛 --> 丙烯草丁钠 --> 2，2-二甲基-N-（4-吡啶基）丙酰胺 --> 反式-1,4-环己二胺
  • 图谱信息:甲基环己烷(108-87-2)核磁图( 1 HNMR) 甲基环己烷(108-87-2)红外图谱(IR1) 甲基环己烷(108-87-2)质谱(MS) 甲基环己烷(108-87-2)核磁图( 13 CNMR)
  • 用途二:是重要的有机溶剂及萃取剂，广泛用于橡胶、涂料、油脂等行业，亦用于有机合成
  • Alfa Aesar:甲基环己胺,99+% Methylcyclohexane, 99+%(108-87-2)
  • 刺激数据:皮肤- 兔 500 微升/ 24小时 轻度; 眼睛- 兔 100 微升/ 24小时 轻度
  • 爆炸物危险特性:与空气混合可爆
  • 蒸气密度:3.4 (vs air)
  • 方法一:甲苯在150℃、约11MPa压力下加氢反应5h，加得到较纯的甲基环已烷。精制时可用浓硫酸、水、5%氢氧化钠溶液和水依次洗涤，用脱水剂干燥，最后进行蒸馏。
  • 类别:易燃液体
  • Sigma Aldrich:108-87-2(sigmaaldrich)
  • MOL 文件:108-87-2.mol
  • F:3-10
  • MSDS 信息:甲基环己烷(108-87-2).msds
  • 能与丙酮、四氯化碳和苯混溶，溶于乙醇和乙醚，不溶于水。易燃。蒸气能与空气形成爆炸性混合物，爆炸极限1.2%-6.7%（体积）。最小致死量（兔，经口）4000mg/kg。有刺激性。
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
  • 用途一:用作溶剂及分析试剂
  • 用途三:用作橡胶、涂料、清漆用溶剂，油脂萃取溶剂等；该品也可用于有机合成；用作校正温度计的标准物。
  • 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
  • TCI Shanghai:甲基环己烷[用于高效液相色谱的溶剂] Methylcyclohexane [for HPLC Solvent],>;99.0%(GC)(108-87-2)
  • 用途四:用作溶剂、色谱分析标准物质，以及作为校正温度计的标准，也用于有机合成
  • 上游原料:脱水剂
  • 职业标准:TWA 1600 毫克/立方米； STEL 2000 毫克/公斤
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 外观性质:无色液体。
  • 急性毒性:口服-大鼠 LD50:>; 3200毫克/公斤;口服-小鼠 LD50:2250 毫克/立方米/24小时
  • 蒸气压:37 mm Hg ( 20 °C)
  • Acros Organics:甲基环己烷 Methylcyclohexane, extra pure, 99%(108-87-2)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. Anhydrous Solvents - Solvent by Application
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkanes 烷烃
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Potassium - Inorganic Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. ACS and Reagent Grade Solvents - Solvent by Application
  5. ReagentPlus® Solvent Grade Products - ACS and Reagent Grade Solvents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Hydrocarbons - Chemical Class
  5. Neats - Hydrocarbons
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent Packaging Options - Solvents
  4. Solvent Bottles - Solvent Packaging Options
  5. Amber Glass Bottles - Solvent Bottles
  6. Spectrophotometric Grade - Amber Glass Bottles
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent by Application - Solvents
  4. Spectroscopy Solvents (IR, NMR, UV/Vis) - Solvent by Application
  5. Spectrophotometric Solvents - Spectroscopy Solvents (IR, NMR, UV/Vis)
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents for HPLC & Spectrophotometry
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Anhydrous Grade Solvents 超干溶剂
  1. Special Specifications 特殊规格产品
  2. Extra Dry Solvents
  3. Supreme Grade

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