1-Amino-2-Naphthol-4-Sulfonic Acid 1-氨基-2-萘酚-4-磺酸

CAS 116-63-2 MFCD00004019

化学结构图

116-63-2
SMILES: Nc1c(O)cc(S(=O)(=O)O)c2ccccc12

化学属性

Mol. FormulaC10H9NO4S
Mol. Weight239.25
Melting Point290 °C
TSCAYes
Solubility不溶
Density1.627
Stability对光敏感
Boiling Point466°C
Appearance 白色或灰色针状结晶，通常含半分子结晶水，在空气中变成玫瑰红色，特别是在潮湿的时候更甚。 不溶于冷水、乙醇、乙醚、苯，溶于热水、热亚硫酸氢钠和碱溶液。

别名和识别编码

Chemical Name1-Amino-2-Naphthol-4-Sulfonic Acid
CAS Number116-63-2
Alfabeta NameAMINOHYDROXYNAPHTHALENESULFONICACID 431-----
MDL NumberMFCD00004019
Synonym 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Amino-3-hydroxynaphthalene-1-sulfonic acid {} {} {} {} {}
Beilstein Registry Number2697469
PubChem Substance ID8316
EC Number204-147-3
Reaxys-RN2697469
Merck Number454
Chemical Name Translation1-氨基-2-萘酚-4-磺酸
LabNetwork Molecule IDLN00158667
InChIInChI=1S/C10H9NO4S/c11-10-7-4-2-1-3-6(7)9(5-8(10)12)16(13,14)15/h1-5,12H,11H2,(H,13,14,15)
Canonical SMILESO=S(C1=C2C=CC=CC2=C(N)C(O)=C1)(O)=O
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds
  • {SNA} Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy

产品应用

  • 酸性媒介染料及酸性络合染料中间体。用于制造酸性络合桃红B；酸性媒介黑R和酸性络合盐GGN；酸性媒介枣BN等。也用于比色法测定磷酸盐及钙盐。

相关文献及参考

  • Key component of the Fiske and Subbarow Reducer for colorimetric determination of phosphate: J. Biol. Chem., 66, 375 (1925); 234, 466 (1959). Reagent for spectrophotometric determination of Si: Microchem. J., 15, 441 (1970).
  • Merck: 14,454
  • Merck: 14,454 Beilstein:14(4)2825

安全信息

Warnings IRRITANT
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
WGK Germany3
RTECSQK1292000
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes Xi
UN Number 2585 3265
GHS Symbol
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupIII

其他信息

  • 上游原料:硫酸 --> 亚硝酸钠 --> 亚硫酸钠 --> 亚硫酸氢钠 --> 焦亚硫酸钠 --> 2-羟基萘
  • 下游产品:1-萘基重氮-2-羟基-4-磺酸内盐 --> 媒介红 7 --> 1,2-萘醌-4-磺酸钾盐 --> 媒介黑 17 --> 中性黑 BL --> 1,2,4-酸氧体 --> 酸性紫90 --> 媒介黑 3 --> 双[3-羟基-4-[(2-羟基-1-萘基)偶氮]-1-萘磺酸铬酸氢二钠
  • 图谱信息:1-氨基-2-萘酚-4-磺酸(116-63-2)核磁图( 1 HNMR) 1-氨基-2-萘酚-4-磺酸(116-63-2)红外图谱(IR2) 1-氨基-2-萘酚-4-磺酸(116-63-2)红外图谱(IR1) 1-氨基-2-萘酚-4-磺酸(116-63-2)核磁图( 13 CNMR) 1-氨基-2-萘酚-4-磺酸(116-63-2)质谱(MS)
  • 用途三:酸性媒介染料及酸性络合染料中间体。用于制造酸性络合桃红B、酸性媒介黑R和酸性络合盐GGN、酸性媒介枣BN等。也用于比色法测定磷酸盐及钙盐。
  • 海关编码:29222100
  • Acros Organics:4-氨基-3-羟基-1-萘磺酸 4-Amino-3-hydroxy-1-naphthalenesulfonic acid, 95%(116-63-2)
  • 用途二:用于制造偶氮染料
  • MOL 文件:116-63-2.mol
  • MSDS 信息:4-Amino-3-hydroxynaphthalene-1-sulphonic acid(116-63-2).msds
  • Sigma Aldrich:116-63-2(sigmaaldrich)
  • 用途四:酸性媒介染料及酸性络合染料中间体。用于制造酸性络合桃红B；酸性媒介黑R和酸性络合盐GGN；酸性媒介枣BN等。也用于比色法测定磷酸盐及钙盐。
  • 1-氨基-2-萘酚-4-磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30009480 1-氨基-2-萘酚-4-磺酸;1,2,4-酸;4-氨基-3-羟基萘-1-磺酸 25g 79元 2011/08/23 30009414 1-氨基-2-萘酚-4-磺酸;1,2,4-酸;4-氨基-3-羟基萘-1-磺酸 25g 12元 2011/04/16 A0367 1-氨基-2-萘酚-4-磺酸 1-Amino-2-naphthol-4-sulfonic Acid 25G 275元
  • TCI Shanghai:1-氨基-2-萘酚-4-磺酸 1-Amino-2-naphthol-4-sulfonic Acid,>;97.0%(T)(116-63-2)
  • Alfa Aesar:4-氨基-3-羟基-1-萘磺酸,ACS,98+% 4-Amino-3-hydroxy-1-naphthalenesulfonic acid, ACS, 98+%(116-63-2)
  • 常含半分子结晶水。能溶于热亚硫酸氢钠和碱溶液，不溶于冷的乙醇；乙醚；苯，微溶于水。在空气中变为粉红色，潮湿时更甚。碱溶液在空气中很快地氧化成棕色，中性溶液略显蓝色荧光。
  • 方法一:以2-萘酚为原料，经碱熔、亚硝化、磺化而得。原料消耗定额：2-萘酚（99%）840kg/t、亚硫酸氢钠（98%）1500kg/t、硫酸（92.5%）1600kg/t。
  • 用途一:用作分析试剂及还原剂，也用于有机合成

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Spectroscopy - Analytical Reagents
  4. UV/Visible (UV/VIS) Spectroscopy - 紫外/可见吸收光谱
  5. UV/Vis Reagents - UV/Visible (UV/VIS) Spectroscopy
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acids 磺酸/亚磺酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonic/Sulfinic Acid Salts
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents

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