CAS 6224-91-5 MFCD00009271-1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔 -LabNovo

1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

CAS 6224-91-5 MFCD00009271

化学结构图

SMILES: CC#C[Si](C)(C)C

化学属性

Mol. Formula	C6H12Si
Mol. Weight	112.24
Refractive index	1.4190 to 1.4210
Boiling Point	99-100°C at 760 mmHg
Density	0.758
Flash Point	4°C
TSCA	No
Melting Point	-69°C
Vapor Density	>;1 (vs air)

别名和识别编码

Chemical Name	1-(Trimethylsilyl)propyne
CAS Number	6224-91-5
Synonym	Trimethyl(prop-1-yn-1-yl)silane {LY} Trimethyl(prop-1-yn-1-yl)silane {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87576914
EC Number	228-314-5
Beilstein Registry Number	1071311
MDL Number	MFCD00009271
Reaxys-RN	1071311
Chemical Name Translation	1-(三甲基硅基)丙炔
InChIKey	DCGLONGLPGISNX-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00194943
Canonical SMILES	CC#C[Si](C)(C)C

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品牌质保精细包装现货库存一流品牌服务

产品应用

经由钯催化的碳环合成高取代的茚类；铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones)；在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3 F;Xi

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P332+P313+P362+P364
P303+P361+P353
P305+P351+P338
P305+P351+P338+P337+P313
P332+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P370+P378
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S29 Do not empty into drains 不要排入下水道；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R11 Highly flammable 非常易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

UN Number 1993 UN 1993 3/PG 2

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Packing GroupII

Hazard Class3

其他信息

Sigma Aldrich:6224-91-5(sigmaaldrich)
TCI Shanghai:1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne,>;98.0%(GC)(6224-91-5)
MOL 文件:6224-91-5.mol
蒸气密度:>;1 (vs air)
1-(三甲基硅基)丙炔价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1123 1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne 5ML 652元 2014/06/02 T1123 1-(三甲基硅基)-1-丙炔 1-(Trimethylsilyl)-1-propyne 25ML 1930元 2010/06/21 223530010 1-(三甲基硅基)丙炔 1-(Trimethylsilyl)-1-propyne 98% 1 GR 423元
Acros Organics:1-(Trimethylsilyl)-1-propyne, 98%(6224-91-5)
用途一:经由钯催化的碳环合成高取代的茚类；铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones)；在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。
Alfa Aesar:1-三甲基甲硅烷基-1-丙炔,98% 1-Trimethylsilyl-1-propyne, 98%(6224-91-5)
TSCA:Yes