4-Hydroxy Thiophenol 对羟基苯硫酚

CAS 637-89-8 MFCD00004850

化学结构图

637-89-8
SMILES: Oc1ccc(S)cc1

化学属性

Boiling Point149-150
Melting Point33-35
Flash Point110°(230°F)
TSCANo
Solubility可溶
Stability对空气和湿度敏感
Density1.255
Mol. FormulaC6H6OS
Mol. Weight126

别名和识别编码

Chemical Name4-Hydroxy Thiophenol
CAS Number637-89-8
Alfabeta NameHYDROXYTHIOPHENOL 4-
MDL NumberMFCD00004850
EC Number211-307-6
Beilstein Registry Number2039306
Synonym 4-HYDROXYTHIOPHENOL 4-HYDROXYTHIOPHENOL 99% 4-Hydroxythiophenol,97% 4-MERCAPTOPHENOL 4-MERCAPTOPHENOL, TECH., 90% 4-Mercaptophenol 4-Sulfanylphenol 4-mercaptophenol 4-巯基苯酚 4-羟基硫代苯酚 4-羟基硫代苯酚,97% 4-羟基苯硫酚 Hydroquinone, monothio- Hydroxythiophenol,94% Monothiohydroquinone PARA-MERCAPTOPHENOL Phenol, p-mercapto- Thiohydroquinone USAF B-57 对巯基苯酚;对羟基苯硫酚;4-巯基苯酚;4-羟基硫代苯酚;4-羟基苯硫 对羟基苯硫酚 對巰苯酚 硫氫醌
PubChem Substance ID240147
Reaxys-RN2039306
Chemical Name Translation对羟基苯硫酚
Wiswesser Line NotationL6V DYJ DUS
LabNetwork Molecule IDLN00007144
InChIKeyBXAVKNRWVKUTLY-UHFFFAOYSA-N
InChIInChI=1S/C6H6OS/c7-5-1-3-6(8)4-2-5/h1-4,7-8H
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiols/Mercaptans

相关文献及参考

  • Beilstein:6,859

安全信息

Warnings AIR SENSITIVE, IRRITANT-HARMFUL, STENCH
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P352+P312+P362+P364
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSMX7175000
Packing GroupIII
UN Number UN1759 2811
Storage condition 充氩保存 对空气敏感,密封保存。 Air Sensitive
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi,C Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 333 mg/kg
SEX/DURATION            : female 11 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 41,43,1990

其他信息

  • MOL 文件:637-89-8.mol
  • 存储注意事项:空气敏感;氮气保护
  • 敏感性:Air Sensitive
  • 图谱信息:4-羟基苯硫酚(637-89-8)质谱(MS) 4-羟基苯硫酚(637-89-8)核磁图( 1 HNMR) 4-羟基苯硫酚(637-89-8)红外图谱(IR1) 4-羟基苯硫酚(637-89-8)核磁图( 13 CNMR)
  • 4-羟基苯硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 H0662 4-羟基苯硫酚 4-Hydroxybenzenethiol 500G 4920元 2011/04/16 H0662 4-羟基苯硫酚 4-Hydroxybenzenethiol 25G 594元 2010/06/21 370630250 4-羟基苯硫酚 4-Mercaptophenol 99% 25 GR 1990元
  • F:10-13-23
  • Hazard Note:Harmful/Irritant
  • Sigma Aldrich:637-89-8(sigmaaldrich)
  • Alfa Aesar:对羟基苯硫酚,97% 4-Hydroxythiophenol, 97%(637-89-8)
  • MSDS 信息:4-Mercaptophenol(637-89-8).msds
  • Acros Organics:4-巯基苯酚 4-Mercaptophenol, 99%(637-89-8)
  • 4-羟基苯硫酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0662 4-羟基苯硫酚 4-Hydroxybenzenethiol 500G 5970元 2014/06/02 H0662 4-羟基苯硫酚 4-Hydroxybenzenethiol 25G 720元 2010/06/21 370630250 4-羟基苯硫酚 4-Mercaptophenol 99% 25 GR 1990元
  • TCI Shanghai:4-羟基苯硫酚 4-Hydroxybenzenethiol,>;95.0%(GC)(T)(637-89-8)
  • 用途一:用作医药、染料中间体

系列性分类