Thionyl bromide 二溴亚砜

CAS 507-16-4 MFCD00011448

化学结构图

507-16-4
SMILES: O=S(Br)Br

化学属性

Mol. FormulaBr2OS
Mol. Weight208
Refractive indexn20/D 1.675(lit.)
Boiling Point48 °C/20 mmHg(lit.)
Vapor Pressure10 mmHg ( 31 °C)
Density2.683 g/mL at 25 °C(lit.)
Melting Point-52 °C(lit.)
TSCAYes
Flash Point156 ºC

别名和识别编码

Chemical NameThionyl bromide
Synonym Schwefligsäurebromid Thionylbromide,97% Sulfinyl dibromide 二溴亚砜 亞硫醯溴 sulfur bromide oxide Thionylbromid thionyl bromide thionyl dibromide 二溴亚砜; 亚硫酰溴 Dibromo sulfoxide SOBr2 Thionl bromide 溴化硫醯基 淡化亚硫酰 THIONYL BROMIDE Sulfur(IV) oxybromide 亚硫酰溴 Sulfuroxy dibromide Sulfur bromide oxide (SOBr2)
MDL NumberMFCD00011448
CAS Number507-16-4
PubChem Substance ID68176
EC Number208-064-3
Merck Number14,9347
Chemical Name Translation二溴亚砜
LabNetwork Molecule IDLN01816009
InChIInChI=1S/Br2OS/c1-4(2)3
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分类

  • {SNA} Bromination, C-X Bond Formation (Halogen), Chemical Synthesis, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: II/25A Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25A Year: 1998 Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules ISBN: 3-540-61713-2 ISBN: 978-3-540-61713-6 Internet Resource: DOI:10.1007/b59072 RefComment: VII, 359 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Packing GroupII
UN Number UN 3264 8/PG 1 3264 UN3264
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S8 Keep container dry 保持容器干燥；
Storage condition Moisture & Light Sensitive 2-8°C
Hazard Codes C
Hazard Class8

其他信息

  • Sigma Aldrich:507-16-4(sigmaaldrich)
  • F:8
  • 蒸气压:10 mm Hg ( 31 °C)
  • 二溴亚砜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L15648 亚硫酰溴, 97% Thionyl bromide, 97% 25g 476元 2010/05/25 L15648 亚硫酰溴, 97% Thionyl bromide, 97% 100g 1266元
  • Alfa Aesar:亚硫酰溴,97% Thionyl bromide, 97%(507-16-4)
  • 敏感性:Moisture & Light Sensitive
  • MOL 文件:507-16-4.mol
  • MSDS 信息:Thionyl bromide (507-16-4).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-X Bond Formation (Halogen) 卤代烃
  4. Bromination - C-X Bond Formation (Halogen)