4-Acetamidobenzenesulfonyl Azide 4-乙酰氨基苯磺酰叠氮
CAS 2158-14-7 MFCD00029626
化学结构图
SMILES: CC(=O)Nc1ccc(S(=O)(=O)N=[N+]=[N-])cc1
化学属性
| Mol. Formula | C8H8N4O3S |
|---|---|
| Mol. Weight | 240 |
| Melting Point | 107-111 |
| TSCA | No |
| Appearance | 白色结晶。熔点107-111℃ |
| Density | 0.884 |
别名和识别编码
| Chemical Name | 4-Acetamidobenzenesulfonyl Azide |
|---|---|
| Synonym | 4-ACETAMIDOBENZENESULPHONYL AZIDE 4-ACETAMIDENZENESULFONYLAZIDE 4-ACETYLAMINOBENZENESULFONYL AZIDE 4-乙酰氨基苯磺酰叠氮 4-乙酰胺基 苯磺酰基叠氮,97% 4-ACETAMIDOBENZENESULFONYL AZIDE 对乙酰氨基苯磺酰叠氮 P-ABSA 对乙酰基氨基苯磺酰叠氮化物 4-乙酰氨基苯磺酸重氮 4-acetamidobenzenesulphon P-ACETAMIDOBENZENESULFONYL AZIDE 4-乙酰氨基苯磺酰叠氮; 对乙酰氨基苯磺酰叠氮 叠 氮 化 4 - 乙 酰 氨 基 苯 磺 酰 4-乙酰胺基叠氮苯磺酰 叠氮化-4-乙酰氨基苯磺酰 |
| Beilstein Registry Number | 2219568 |
| PubChem Substance ID | 87560767 |
| CAS Number | 2158-14-7 |
| MDL Number | MFCD00029626 |
| Reaxys-RN | 2219568 |
| Chemical Name Translation | 4-乙酰氨基苯磺酰叠氮 |
| LabNetwork Molecule ID | LN00223898 |
| InChI | InChI=1S/C8H8N4O3S/c1-6(13)10-7-2-4-8(5-3-7)16(14,15)12-11-9/h2-5H,1H3,(H,10,13) |
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分类
- {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents, Various Azides
- {SNA} Azidation/Diazo Transfer, Azides, Building Blocks, C-X Bond Formation (Non-Halogen), Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Nitrogen Compounds, Organic Azides, Organic Building Blocks, Synthetic Reagents,
产品应用
- 有机叠氮化试剂，叠氮转移试剂：用于合成α-叠氮酯。
相关文献及参考
- Beilstein:14(3)2107
- For a further example, see: Org. Synth. Coll., 9, 155 (1998).
- Diazo transfer agent. Recommended as a safer alternative to tosyl azide for diazo transfer reactions, in the presence of a base, e.g. Et3N or DBU, with active methylene compounds. A further advantage of the reagent is that the by-product sulfonamide is removable by trituration with water: Synth. Commun., 17, 1709 (1987). For illustrative examples, with subsequent cyclization using Rhodium(II) acetate, L15152, as a route to highly substituted furans, see: Tetrahedron, 44, 3343 (1988); Org. Synth. Coll., 9, 422 (1998):
安全信息
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H303 May be harmfully swallowed 吞食可能有害
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:2158-14-7.mol
- Sigma Aldrich:2158-14-7(sigmaaldrich)
- 用途一:有机叠氮化试剂，叠氮转移试剂：用于合成α-叠氮酯。
- TCI Shanghai:4-乙酰氨基苯磺酰叠氮 4-Acetamidobenzenesulfonyl Azide,>;97.0%(N)(2158-14-7)
- 4-乙酰氨基苯磺酰叠氮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010181 对乙酰基氨基苯磺酰叠氮化物 25g 600元 2011/04/16 A1786 4-乙酰氨基苯磺酰叠氮化物 4-Acetamidobenzenesulfonyl Azide 25G 814元 2010/05/25 L15916 4-乙酰胺基 苯磺酰基叠氮,97% 4-Acetamidobenzenesulfonyl azide, 97% 5g 224元
- 图谱信息:4-乙酰氨基苯磺酰叠氮(2158-14-7)红外图谱(IR2) 4-乙酰氨基苯磺酰叠氮(2158-14-7)红外图谱(IR1)
- Alfa Aesar:4-乙酰胺基苯磺酰基叠氮,97% 4-Acetamidobenzenesulfonyl azide, 97%(2158-14-7)
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